Department of Mechanical Engineering
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Item Energy from biomass and plastics recycling: a review(Taylor and Francis, 2021-01-01) Samuel Oluwafikayo Adegoke; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Chiebuka Timothy Nnodim; Ayokunle Olubusayo Balogun; Olugbenga Adebanjo Falode; Seun Olawumi AdetonaThe sustainability of fossil fuel is not guaranteed as it is gradually depleting. Alternative ways to this challenge are to generate biofuel from biomass and plastic solid wastes. Many studies have been done on the actualization of these alternatives. Hence, this study accumulates research from multidiscipline for the purpose of advancing biofuel production for sustainable energy. The necessary information needed by scientists having interest in biofuel production, including government policy, biomass selection, different conversion techniques and different ASTM standards for biodiesel properties are entrenched in this study. For vast biofuel production, there is a need for a collaborative work among fields from microbiologist, biochemist to engineering for the development of innovations, growth of cells, understanding of genetic engineering of algae strains and optimization of biofuel production. Also, a review on the recovery and recycling process of plastic solid waste was done. This is to ensure that the use of plastic solid waste to support energy sustenance will lead to no energy is wasted. Various ASTM standards for investigating the different properties of bio-oil were reviewed. The numerous plastic wastes that have not been utilized in the production of biofuel can be investigated to reduce the environmental pollution.Item Pathways for the Valorization of Animal and Human Waste to Biofuels, Sustainable Materials and Value-Added Chemicals(MDPI, 2023-03-06) Jude A. Okolie; Toheeb Jimoh; Olugbenga Akande; Patrick U. Okoye; Chukwuma C. Ogbaga; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Fatih Güleç; Andrew Nosakhare AmenaghawonHuman and animal waste, including waste products originating from human or animal digestive systems such as urine, feces, and animal manure, have constituted a nuisance to the environment. Inappropriate disposal and poor sanitation of human and animal waste often cause negative impacts on human health through contamination of the terrestrial environment, soil, and water bodies. Therefore, it is necessary to convert these wastes into useful resources to mitigate their adverse environmental effect. The present study provides an overview and research progress of different thermochemical and biological conversion pathways for the transformation of human- and animal-derived waste into valuable resources. The physicochemical properties of human and animal waste are meticulously discussed as well as nutrient recovery strategies. In addition, a bibliometric analysis is provided to identify the trends in research and knowledge gaps. The results reveal that the U.S.A, China and England are the dominant countries in the research areas related to resource recovery from human or animal waste. In addition, researchers from the University of Illinois, the University of California Davis, the Chinese Academy of Science and Zhejiang University are front runners in research related to these areas. Future research should be centred on developing technologies for the on-site recovery of resources, exploring integrated resource recovery pathways, and exploring different safe waste processing methods.Item Effect of copper addition and solution heat treatment on the mechanical properties of aluminum alloy using formulated bio-quenchant oils(Engineering and Applied Science Research, 2020-01-01) Adekunle A.S.; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Omoniyi P. O.; Gbadamosi T. A.; Jamiu Kolawole OdusoteAddition of copper and use of solution heat treatment solution with bio degradable vegetable oils as quenchants has great potential to improve the mechanical properties of aluminum and its alloys. In this study, copper was added to as-received Al- Si-Mg alloy to produce Al-Si-Cu-Mg alloy. The specimens were quenched with blended bleached bio-quenchant oils and a petroleum-based oil after solution heat treatment. The alloy was heat treated at 500℃, soaked for 20 minutes in a muffle furnace before quenching in the formulated bio-quenchant oils. The cooling properties, mechanical properties and microstructure of the solution treated specimens were determined. Blended bleached melon (BBM) oil was observed to have offered a higher cooling rate of 49.3 ℃ s-1 compared to the petroleum-based (PB) oil with a cooling rate of 25.8 ℃ s-1. Blended bleached melon oil exhibited the highest quench severity value of 1.0074 m-1, while petroleum-based oil was 0.6133 m-1. The as-received alloy and as-cast alloy specimens exhibited tensile strength values of 125.33 and 131.37 N mm-2, respectively, while a higher tensile strength value of 139.30 Nmm-2 was obtained using the blended bleached melon oil. The highest Rockwell hardness number, 61.00 HRB, was obtained using blended bleached melon oil. The overall mechanical properties of specimens improved after the addition of copper and heat treatment in various bio-quenchant oilsItem Corrosion rates of green novel hybrid conversion coating on aluminium 6061(Elsevier, 2020-08-19) Makanjuola Oki; A.A. Adediran; Peter Pelumi Ikubanni; O.S. Adesina; Adekunle Akanni Adeleke; S.A. Akintola; F. Edoziuno; A. AleemThe use of chromate conversion coatings have been limited by several protocols as a result of their carcinogenicity and toxicity towards humans and the environment. Searches are ongoing for chromate replacement in coating baths and processes. This paper describes the comparison among the corrosion rates of a novel hybrid conversion coating derived from water extracts of hibiscus sabdariffa calyx in conjunction with ammonium molybdate, a molybdate conversion coating and the so-called chromate conversion coating. Potentiodynamic polarization measurement in 3.5 wt% sodium chloride solution was employed in ranking the coatings as sabdariffa molybdate being more corrosion resistant than chromate, which in turn out performed molybdate.Item Influence of temperature on the chemical compositions and microstructural changes of ash formed from palm kernel shell(Elsevier, 2020-09-30) Peter Pelumi Ikubanni; Makanjuola Oki; Adekunle Akanni Adeleke; Adediran, A.A; O.S. AdesinaThis study investigated the characteristics of raw palm kernel shell (raw PKS) and the influence of temperature variation on palm kernel shell ash (PKSA). The PKSA was obtained under different temperature regimes of 900, 1000, and 1100°C. The characterization of the samples was carried out using X-ray Fluorescence (XRF), Fourier Transform Infrared (FTIR), X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) with attached Energy Dispersive X-ray (EDX) facilities. The results showed that moisture and ash contents and the density of raw PKS were 6.56%, 8.86%, and 745 kg/m3, respectively. The colour of the pulverized PKS was dark brown, as observed by visual examination based on standard colour gradation. This colour transformed into various shades of brown when PKS was subjected to different temperature regimes to form PKSA. The XRF analysis showed that silica is the main constituent of the raw PKS and PKSA samples. Silica content in the PKSA increased with the rise in the heating temperature. The FTIR and EDX spectra confirmed the predominance of silicon compounds with functional groups associated with silanol and siloxane. Also, XRD analysis revealed that the silica contents in the samples are quartz, while SEM examinations indicated that temperature increases during processing influenced the microstructure through the reduction of pore concentration in the samples. The silica obtained from the PKSA would find applications in metal matrix composites as partial reinforcing materials.Item Development and characterization of wood-polypropylene plastic-cement composite board(Elsevier, 2020-05-16) I. O. Ohijeagbon; Peter Pelumi Ikubanni; Adekunle Akanni Adeleke; Adekunle Akanni Adeleke; Vincent T. Mustapha; John A. Olorunmaiye; Imhade P. OkokpujieThe utilization of agricultural residues and industrial wastes such as plastics to complement the use of solid wood in the manufacturing of composite panels presents an effective and efficient way of waste management for sustainable utilization of resources, especially in developing countries. Thus, the present study aimed at developing a cheap, safe, and energy-efficient composite board for effective house partitioning from sawdust and polypropylene plastic using cement and expanded polystyrene (EPS). Composite boards were developed from the blend of sawdust and polypropylene plastic using cement and expanded polystyrene (EPS) as adhesives. The composite boards were made by varying the sawdust-polypropylene ratio as well as the cement-EPS ratio. A constant load of 0.2 MPa was used in compacting the materials in a prepared aluminum mold under a hydraulic press machine. Physico-mechanical properties of the composite board such as density, water absorption, moisture content, compressive strength, tensile strength and flexural strengths were evaluated. The density of the composite boards varied from 490 to 630 kg/m3. The moisture content ranged from 6.04 to 9.09% while the water absorption ranged from 30 to 80% after 2 and 24 h immersion. The highest flexural, tensile and compressive strength for the composite boards were 7.10, 1.52, and 3.72 MPa, respectively. The composite samples met all the requirements of a partitioning wall except for flexural strength based on IS3087 standard. Cement and EPS were found to be suitable as adhesive for the development of composite boards from sawdust and polypropylene.Item Physico-chemical characterization, thermal decomposition and kinetic modeling of Digitaria sanguinalis under nitrogen and air environments(Elsevier, 2021-06-12) Ayokunle O. Balogun; Adekunle Akanni Adeleke ; Samuel Oluwafikayo Adegoke; Armando G. McDonald; Peter Pelumi Ikubanni; Abdulbaset M. AlayatThe study undertook the thermal degradation of a tropical grass species, Digitaria sanguinalis, in nitrogen (pyrolysis) and air (combustion) atmospheres through thermogravimetric analysis as well as comparative kinetic investigation. The differential (Friedman) and integral (Flynn-Wall-Ozawa and Straink) isoconversional methods in conjunction with the Coats-Redfern method were utilized. This was to obtain the kinetic parameters and also predict the probable reaction mechanisms involved in the decomposition process. Before the thermal and kinetic investigations, the grass was analyzed for its physical, chemical, and structural properties utilizing diverse wet-chemistry and spectroscopic techniques. This research attempt is part of a larger project designed to investigate a couple of local grass species, which are invasive by nature, as potential energy crops for pyrolytic and combustion applications. The grass had a fixed carbon content of 17.85% and a calorific value of 13.7 MJ kg−1. The fatty acids detected were from C12 (lauric acid) to C24 (lignoceric acid), with the three most abundant being palmitic (94 mg/g extract), linoleic (27 mg/g extract), and oleic (19 mg/g extract) acids. The average residual weight in air (25.3%) was relatively less than in nitrogen (38.7%), affirming the higher rate of reaction in an oxidative process (combustion). The activation energy profiles in both atmospheres were markedly different, as shown by the Flynn-Wall-Ozawa technique for a conversion ratio of 0.1–0.2 (nitrogen, 149 kJ/mol; air, 177 kJ/mol) and 0.65–0.8 (nitrogen, 366 kJ/mol; air, 170 kJ/mol). Of all the models tested, the model-fitting technique indicates that the chemical reaction and diffusional models play predominant roles in the thermal decomposition of the grass under investigation. The thermal degradation of Digitaria sanguinalis proceeded mainly as complex multi-step reaction mechanisms. Aside from the potential suitability of the grass species for bioenergy applications and biofuels production, it also demonstrated huge capability for biochemical extraction. Future work will incorporate the kinetic data for the associated thermochemical processes development, and the design and optimization of reactors/combustors.