Faculty of Engineering
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Item Comparative studies of machine learning models for predicting higher heating values of biomass(Institution of Chemical Engineers (IChemE), 2024-06-29) Adekunle Akanni Adeleke; Adeyinka Adedigba; Steve Adeshina; Peter Pelumi Ikubanni; Mohammed S. Lawal; Adebayo Isaac Olosho; Halima S. Yakubu; Temitayo Samson Ogedengbe; Petrus Nzerem; Jude A. OkolieThis study addresses the challenge of efficiently determining the higher heating value (HHV) of biomass, a crucial parameter in large-scale biomass-based energy systems. The conventional method of measuring HHV using an oxygen bomb calorimeter is time-consuming, expensive, and less accessible to researchers, particularly in developing nations. To overcome these limitations, we employed four machine learning (ML) models, namely Random Forest (RF), Decision Tree (DT), Support Vector Machine (SVM), and Extreme Gradient Boosting (XGBoost). These models were developed by using proximate and ultimate analysis parameters as input features. Up to 200 datasets were compiled from literature and used for the ML models. Our results demonstrate the effectiveness of all ML models in accurately predicting the HHV of biomass materials. Notably, the XGBoost model exhibited superior performance with the highest R-squared (R2) values for both training (0.9683) and test datasets (0.7309), along with the lowest root mean squared error (RSME) of 0.3558. Key influential input features identified for HHV prediction include carbon (C), volatile matter (Vm), ash, and hydrogen (H). Consequently, this research provides a reliable alternative for predicting HHV without the need for costly and time-intensive experimental measurements, facilitating broader accessibility in biomass energy research.Item Simulation Technology in Renewable Energy Generation: A Review(International Conference on Multidisciplinary Engineering and Applied Sciences (ICMEAS), 2023-11-01) Adekunle Akanni Adeleke; Petrus Nzerem; Ayuba Salihu; Esther Nneka Anosike-Francis; Adebayo Isaac Olosho; Kpabep Kerein Kalenebari; Yuguda Abdullahi Muhammad; Waliyi Adekola Adeleke; Moses Oluwatobi FajobiThe escalating energy consumption rates and the alarming environmental impacts associated with fossil fuel usage have driven global attention towards alternative energy sources. While nuclear power has emerged as one such alternative, concerns about past reactor accidents and the health effects of radiation release have limited its widespread adoption. Renewable energy, on the other hand, offers a promising solution with minimal environmental harm compared to nuclear power. However, the intermittent nature of renewable energy sources and their inability to consistently supply power present significant challenges for nations aiming to harness these abundant resources. To address these challenges, the integration of simulation technology into energy generation processes has proven instrumental. By employing simulation tools, it becomes possible to identify, control, and even eliminate factors that may hinder energy generation and efficiency. Furthermore, simulation technology enables accurate predictions of the expected energy output from renewable sources. This paper presents a comprehensive review of the recent advancements and applications of simulation technology in renewable energy generation. It elucidates how simulation technology has been successfully integrated into renewable energy systems and discusses its potential to enhance the efficiency of renewable energy generation.Item A Review of the Physical, Optical and Photoluminescence Properties of Rare Earth Ions Doped Glasses(TRENDS IN SCIENCES, 2024-10-22) Serifat Olamide Adeleye; Adekunle Akanni Adeleke; Petrus Nzerem; Adebayo Isaac Olosho; Esther Nneka Anosike-Francis; Temitayo Samson Ogedengbe; Peter Pelumi Ikubanni; Rabiatu Adamu Saleh; Jude A. OkolieDoping glasses with rare-earth ions have garnered significant attention among researchers worldwide. This interest stems from the widespread utilization of rare-earth ions to enhance the optical characteristics of host glasses and exploit the unique spectroscopic properties arising from their optical transitions in the intra-4f shell. Thus, this study reviewed the exceptional potential of rare-earth ion-doped glasses (REIs) in various applications such as solid-state lasers, photonic devices, communication optical fibers, and white light emission. Various methods for the fabrication of glass such as direct melt quenching, sol-gel, ion exchange, sputtering and co-doping techniques were reviewed extensively. The Specific focus was on the physical, optical and photoluminescence properties of glasses produced from glass formers co-doped with rare earth ions. The investigation centers on the comprehensive current applicability of REI-doped glasses. The review concludes based on the physical, optical and photoluminescence properties of rare earth ion-doped glasses that they are extremely useful in photonics, lasers, biomedical and optical communication applications.Item Green Corrosion Inhibition Practices(IEEE, 2023-11-01) Petrus Nzerem; Adekunle Akanni Adeleke; Ayuba Salihu; Esther Nneka Anosike-Francis; Adeiza Avidime Samuel; Adebayo Isaac Olosho; India Chiazokam Odezugo; Jachimike Agbo Samuel; Peter Pelumi IkubanniCorrosion poses significant challenges for industries worldwide, causing financial losses, safety risks, and environmental issues. To address these concerns, there has been a shift towards sustainable corrosion prevention techniques. This review presents a summary of corrosion, corrosion inhibitors, and specifically focuses on green corrosion inhibitors. It discusses relevant literature exploring various types of green inhibitors to mitigate corrosion. Additionally, it highlights recent progressions in the application of green corrosion inhibitors. The insights presented in this paper enable researchers, engineers, and business experts to adopt sustainable corrosion prevention solutions.Item Formed Coke from Coal and Plastic: A Review(IEEE, 2023-02-28) Adekunle Akanni Adeleke; Petrus Nzerem; Ayuba Salihu; Jamiu Kolawole Odusote; Adebayo Isaac Olosho; Peter Pelumi Ikubanni; Yazeed Abubakar Mohammed; Samuel Chijoke Lawrence; Temitayo Samson Ogedengbe; Adeiza Avidime SamuelItem Characterization of Wheat Husk ASH and Calcined Eggshell as Potential Glass Former(IEEE, 2023-11-01) Serifat Olamide Adeleye; Adekunle Akanni Adeleke; Petrus Nzerem; Peter Pelumi Ikubanni; Ayuba Salihu; Adebayo Isaac OloshoNumerous agricultural byproducts, such as rice husk and straw, bagasse from sugar cane, palm kernel shell, wheat husk and straw, corn cobs, etc, are highly desired for the production of renewable energy and are seen as potential raw materials for high-value products. Because they can be used to extract quality silica and Calcium oxide for borosilicate glass production, this research has demonstrated that these wastes have a significant end value. X-ray diffraction (XRD) spectroscopy, Fourier transform infrared spectroscopy (FT-IR), and X-ray fluorescence spectroscopy (XRF) were used to characterize the calcined waste eggshell and wheat husk ash for crystal type, compound identification, and chemical composition. The findings demonstrated that the amount of silica and calcium oxide obtained from agricultural waste could be a suitable alternative source for making glass, with calcined eggshells having a calcium oxide content of 91.7% and wheat husk ash having a silica content of 71.3%. The potential for utilizing the CaO and amorphous silica in the formation of glass is thus intriguing.Item Development of hydrometallurgical purification process for Nigerian gypsum ore in hydrochloric acid. Part II: Recovery of pure gypsum from leached liquor(IEEE, 2023-11-01) Adebayo Isaac Olosho; Folahan Amoo Adekola; Adekunle Akanni Adeleke; Alafara Abdullahi Baba; Kalenebari Kerein Kpabep; Suleiman Suleiman Abba; Divine Uwaoma Okezie; Temitayo Samson Ogedengbe; Ayuba SalihuAs the world grapples with the challenges of resource scarcity and sustainability, the need to develop indigenous raw materials has gained paramount importance. To achieve self-sufficiency and reduce dependence on foreign sources, harnessing hydrometallurgical processes to extract valuable elements from ores presents a promising solution. Raw gypsum from Postikum, Nigeria, was leached in hydrochloric acid to obtain a pure calcium sulphate dihydrate. The dissolution kinetics have been reported elsewhere. This present study focused on optimizing the recovery of pure gypsum by varying acid concentration, temperature, and solid-liquid ratio. Additionally, the recyclability of regenerated hydrochloric acid was tested. The characterization of the raw gypsum ore (RWG), leached residue (LR), and recovered pure gypsum (RCG) was done using SEM-EDS, XRF, and XRD, respectively. The recovered gypsum was characterised by a brilliant white colour in contrast to the initial brown colour of the ore. XRF results show that RWG contains 50.48% SO3 while RCG contains 57.72 %. XRD results revealed that RWG contains gypsum, magnesite, mordenite, witherite, and calcite, LR contains mordenite, witherite and quartz while RCG consists of gypsum crystal phase only with no impurities. Remarkably, 85% RCG was successfully recovered at the fourth recycle stage of HCl lixiviant. These findings demonstrate that hydrometallurgical treatment of gypsum ore with hydrochloric acid can produce very pure gypsum.Item Renewable Energy Conversion from Biomass(International Conference on Multidisciplinary Engineering and Applied Sciences (ICMEAS-2023), 2023-11-01) Adekunle Akanni Adeleke ; Petrus Nzerem; Ayuba S.; Esther Nneka Anosike-Francis; Peter Pelumi Ikubanni; Adebayo Isaac Olosho; Abdulrasheed Ado; Adeiza Avidime Samuel; Jakada K.The global impacts of fossil fuels have driven governments and companies to investigate other methods of energy production for the benefit of society. The utilization of biomass in energy validates the possibility to replace non-renewable sources of energy. Bioenergy is obtained from a wide variety of sources, including rice husks, bagasse, wood chippings, and sawdust. This article presents an examination of the techniques employed in the conversion of biomass into energy that is suitable for practical applications, ecologically friendly and also the rates at which biomass power is consumed worldwide.Item A Review on Biomass Briquettes as Alternative and Renewable Fuels(IEEE, 2023-02-28) Adekunle Akanni Adeleke; Petrus Nzerem; Ayuba Salihu; Esther Nneka Anosike-Francis; Adebayo Isaac Olosho; Etowa Emmanuel Obasesam; Sakeenah Sadiq Abubakar; Dakut John Yerima; Khaleel JakadaThe adverse effects of the combustion of fossil fuels on humanity and the environment have made it vital to discover eco-friendly, sustainable, and renewable energy alternatives. Globally, there exists loose biomass, which is agricultural and cultural waste that can be utilised to produce briquettes, a type of solid fuel. Briquettes have played a significant role in the energy generation economies of both developing and developed nations. The production of briquettes involves a series of activities, including collection, transportation, storage, processing, and densification of the feedstock to meet predetermined quality parameters. Rice husk, corn stalk, wheat straw, cassava stalk, groundnut shell, olive husk, palm kernel shell and coconut shell are among the feedstocks for briquettes. In order to increase the cohesive strength of the briquettes, binders are incorporated during the densification process. This study aims to investigate the current state of research regarding the utilisation of biomass-derived briquettes as a viable substitute for traditional fuels. To achieve this objective, a comprehensive analysis of recent literature published between 2017 and 2023 is conducted. This study encompasses essential subtopics, including the accessibility of biomass, the selection of binders, the parameters of the briquette process, and the equipment used for briquetting.Item A Review on Extraction of Rare Earth Elements (REEs) From Coal Using Acid Leaching(IEEE, 2023-11-01) Rabiatu Adamu Saleh; Abdullahi Gimba; Adekunle Akanni Adeleke; Adebayo Isaac Olosho; Taofeek Sunmonu; Petrus Nzerem; Ayuba Salihu; Chinomso OdimbaCoal has become a feasible source of rare earth elements (REEs; the 14 stable lanthanides, scandium, and yttrium). It is believed to contain significant amounts of rare earth elements, making it a primary source of REEs which serves as basic raw materials in the production of renewable energy. This review established the feasibility of recovering REEs from coal using acid leaching method. It discusses; the sourcing of REEs from coal, the applications of REEs and acid leaching as an effective hydrometallurgical method for extracting REEs from coal. It also examined the efficiency of methods used by other researchers in extracting REEs from coal. However, the potential of acid leaching as a solution to issues such as: difficult leaching conditions, low recovery and the use of expensive chemicals has not been fully investigated. For a better choice in the extraction of REEs from coal, more study and review are necessary.