Department of Petroleum & Gas

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Author: search.filters.author.Petrus NzeremSubject: search.filters.subject.Cellulose

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    Effect of Raw and Delignified Banana Stem (Musa Cavendish) On the Rheological and Filtration Loss Properties of Water Based Mud
    (NJEAS, 2023-10-12) Ayuba Salihu; Ahmed Abubakar; Petrus Nzerem; Abdullahi Gimba; Khadijah Ibrahim; Ikechukwu Okafor; Khaleel Jakada
    In compliance with environmental laws and safety rules, oil and gas companies have taken necessary steps to eradicate the use of toxic chemicals conventionally used in drilling muds, thereby promoting biodegradable alternatives. This research was carried out to investigate the effect of two banana stem samples; Raw Banana Stem (RBS) and Delignified Banana Stem (DBS) as potential and proficient viscosifiers and fluid loss control agents in water based mud. The rheological properties evaluated include plastic viscosity (cP), apparent viscosity (cP), yield point (Ib/100ft2) and gel strength (Ib/100ft2) at 10 seconds and 10 minutes. Filtration loss properties evaluated include filter cake thickness (mm) and fluid loss volume (ml). Each drilling mud sample was prepared using 350 ml, 20 g bentonite and varying contents (g) of carboxyl methyl cellulose (CMC), RBS and DBS. A mixer was used to mix the mud homogenously; the rheological properties were calculated using a viscometer while the filtration loss properties were calculated using a filter press. The results and analysis were compared to the effects of commercially available carboxymethyl cellulose to validate its properties. RBS and DBS improved the rheological properties of the mud sample contents of 3 g, 5 g, 7 g and 9 g. At contents of 5 g, 10 g, 15 g and 20 g, RBS and DBS samples provide significant fluid loss control and their results are similar to the results of CMC. RBS has a fluid loss volume increase of 6.84 %, 5.69 %, 17.12 % and 8.06 % from CMC’s results at slightly similar filter cake thickness while DBS has a fluid loss volume increase of 15.59 %, 15.09 %, 27.55 % and 15.35 % from CMC’s result. The data obtained from the experiments showed both banana samples can be used as environmentally friendly viscosifiers and fluid loss control agents.
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    Isolation, characterization and response surface method optimization of cellulose from hybridized agricultural wastes
    (Scientifc Reports, 2024-06-21) Hauwa A. Rasheed; Adekunle Akanni Adeleke; Petrus Nzerem; Adebayo Isaac Olosho; Temitayo Samson Ogedengbe; Seun Jesuloluwa
    This study explores the utilization of eight readily available agricultural waste varieties in Nigeria—sugarcane bagasse, corn husk, corn cob, wheat husk, melina, acacia, mahogany, and ironwood sawdust—as potential sources of cellulose. Gravimetric analysis was employed to assess the cellulose content of these wastes, following which two selected wastes were combined based on their cellulose content and abundance to serve as the raw material for the extraction process. Response Surface Methodology, including Box-Behnken design, was applied to enhance control over variables, establish an optimal starting point, and determine the most favorable reaction conditions. The cellulose extracted under various conditions was comprehensively examined for content, structure, extent of crystallinity, and morphological properties. Characterization techniques such as X-ray Diffraction, Scanning Electron Microscopy, and Fourier Transform Infrared Spectroscopy were employed for detailed analysis. Compositional analysis revealed sugarcane bagasse and corn cob to possess the highest cellulose content, at 41 ± 0.41% and 40 ± 0.32% respectively, with FTIR analysis confirming relatively low C=C bond intensity in these samples. RSM optimization indicated a potential 46% isolated yield from a hybrid composition of sugarcane bagasse and corn cob at NaOH concentration of 2%, temperature of 45 °C, and 10 ml of 38% H2O2. However, FTIR analyses revealed the persistence of non-cellulosic materials in this sample. Further analysis demonstrated that cellulose isolated at NaOH concentration of 10%, temperature of 70 °C, and 20 ml of 38% H2O2 was of high purity, with a yield of 42%. Numerical optimization within this extraction condition range predicted a yield of 45.6% at NaOH concentration of 5%, temperature of 45 °C, and 20 ml of 38% H2O2. Model validation confirmed an actual yield of 43.9% at this condition, aligning closely with the predicted value. These findings underscore the significant potential of combinning and utilizing agricultural wastes as a valuable source of cellulose, paving the way for sustainable and resource-efficient practices in various industrial applications.