Department of Petroleum & Gas
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Item Production of Biodiesel from Waste Cooking Oil by Transesterification Process using Heterogeneous Catalyst(NIJEST, 2021-12-07) Ayuba Salihu; Mahmood A. A.; Gimba S. B.; Petrus Nzerem; Ikechukwu OkaforNon-renewable diesel from fossil has been considered as potentially carcinogenic with serious harmful effect to human health and to the environment. This study aimed to produce a renewable diesel –biodiesel- via transesterification of waste cooking oil (WCO), investigated and determined the most suitable amongst various types of heterogenous catalysts (viz a viz KOH/CaCO3, KOH/CaO and KOH/K2CO3). The chemical and physical characterisation of the biodiesel was been carried out. Among the catalysts investigated, KOH/CaCO3 catalyst showed the best catalytic performance in terms of % yield and better fuel quality in density, acid value, viscosity and free fatty acid. The reason for this performance may be due to its most basic characteristic than the others. As a result, this catalyst was selected for the optimisation study. At the optimum reaction conditions of 10 wt% catalyst loading and 1:10 oil to methanol feed mole ratio, triglycerides conversion was highest, 98.12%. The characterisation results shows that the parameters tested (i.e. density, viscosity, acid value and free fatty acid) meet the strict requirements of the biodiesel standard and therefore, the produced fuel can be used in place of the petrol diesel.Item Determination of the Optimal Blend Ratio of Hydrogen in Natural Gas System Using Physical Properties as Basis(ICMEAS, 2023-11-01) Ayuba Salihu ; Ikechukwu Okafor; Aniezi Okoro Daniel; Abdullahi Gimba ; Petrus NzeremThe Determination of the optimal blend ratio of hydrogen in natural gas systems using physical properties as a basis is an important research topic given the increasing use of hydrogen as an alternative fuel source. This research aims to determine the optimal blend ratio of hydrogen in a natural gas system using physical properties such as its Composition, Heating Value, Density, and Wobbe index as the basis of evaluation. Samples of consumer-grade Natural gas and clean Hydrogen gas were sourced in Nigeria. Both samples were used for blending and laboratory analysis. The blend volume ratios of Natural Gas (NG) and Hydrogen analyzed were 9:1, 8:2, 7:3, 6:4, & 5:5 using a Gasometer and Gas Chromatography Machine (CG). The experiment results provided valuable insights into the potential feasibility of replacing natural gas systems with a Hydrogen-Natural gas blend. The result obtained indicated about 2.06% reduction in percentage methane content, 26.35% reduction in gas density, 19.97% reduction in heating value (HHV), 5% reduction Wobbe index for every 10% increment of Hydrogen Ratio. This implies that blending carbon-neutral hydrogen gas into the natural gas systems for the purpose of decarbonization requires adequate compensation for expected changes in properties like heating value, flow dynamics, and process handling. The EUROMOT specification recommends that the percentage change in the wobbe index should be within the limit of +4% and -4% as an acceptable limit of interchangeability of fuel gas. Using the EUROMOT specification on Wobbe index, further numerical analysis affirmed that Natural Gas blended with as much as 25.74% Hydrogen can effectively be a substitute for fuel gas systems that are presently using Natural Gas.Item Simulation Technology in Renewable Energy Generation: A Review(International Conference on Multidisciplinary Engineering and Applied Sciences (ICMEAS), 2023-11-01) Adekunle Akanni Adeleke; Petrus Nzerem; Ayuba Salihu; Esther Nneka Anosike-Francis; Adebayo Isaac Olosho; Kpabep Kerein Kalenebari; Yuguda Abdullahi Muhammad; Waliyi Adekola Adeleke; Moses Oluwatobi FajobiThe escalating energy consumption rates and the alarming environmental impacts associated with fossil fuel usage have driven global attention towards alternative energy sources. While nuclear power has emerged as one such alternative, concerns about past reactor accidents and the health effects of radiation release have limited its widespread adoption. Renewable energy, on the other hand, offers a promising solution with minimal environmental harm compared to nuclear power. However, the intermittent nature of renewable energy sources and their inability to consistently supply power present significant challenges for nations aiming to harness these abundant resources. To address these challenges, the integration of simulation technology into energy generation processes has proven instrumental. By employing simulation tools, it becomes possible to identify, control, and even eliminate factors that may hinder energy generation and efficiency. Furthermore, simulation technology enables accurate predictions of the expected energy output from renewable sources. This paper presents a comprehensive review of the recent advancements and applications of simulation technology in renewable energy generation. It elucidates how simulation technology has been successfully integrated into renewable energy systems and discusses its potential to enhance the efficiency of renewable energy generation.Item Performance Evaluation of Nanocellulose Synthesised from Yam Peels as a Fluid Loss Additive in Water Based Mud(Society of Petroleum Engineers, 2023-07-30) Khadijah Ibrahim; Petrus Nzerem; Ayuba Salihu; Abdullahi Gimba; Oghenerume Ogolo; Ajiri Otedheke; Rabiatu Adamu; Aisha KarofiDrilling fluids play a variety of roles in order to achieve a smooth and cost-effective drilling operation, the most important of which is their ability to seal permeable walls of the formation through the formation of a desirable mud cake, thereby reducing fluid loss. This study is targeted at evaluating the performance of nano cellulose, cellulose microfibrils synthesised from yam peels as a fluid loss additive and also its effect on the other properties of the drilling mud. The use of nano-cellulose is due to smaller particles forming better impermeable packing that will plug the permeable pore of the mud cake, as well as its ability to hold water. The nano cellulose was synthesised using bleaching, alkali treatment, and acid hydrolysis, and its quality was assessed using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy, which confirmed the removal of some non-cellulose components as well as changes in surface morphology. The results of the experiment revealed that nano cellulose had an effect on the pH, rheological properties, and filtration properties of the drilling mud. The results also show that adding 1.5 g of nanocellulose reduced fluid loss by 8.13 %, and thus it can be concluded that yam peels nanocellulose will be an effective additive at higher concentrations compared to the Carboxyl Methyl Cellulose, a commercial additive.Item Performance Analysis of Cowpea Skin, Sugar Cane Rind and Yam Bark as Additives in Water-Based Drilling Mud(International Conference on Multidisciplinary Engineering and Applied Science (ICMEAS) Authors:, 2023-11-01) Petrus Nzerem; Oghenerume Ogolo; Blessing O. Alade; Ajiri Otedheke; Ayuba Salihu; Jakada K.Drilling operations require the use of drilling fluid with optimum characteristics. Desired drilling fluid properties is typically controlled using additives. Due to the environmental and safety impact of synthetic additives, this research investigated the use of degradable food waste namely cowpea skin powder (CSP), sugarcane rind powder (SRP) and yam bark powder (YP) as additives in water-based drilling mud. To check the potential of these biodegradable food waste as additives, their elemental composition and approximate composition were ascertained using Scanning electron microscope with energy dispersive x-ray spectroscopy (SEM EDS) and proximate analysis. The method used included the collection, cleaning, drying and grinding each of the food waste (sugarcane rind, cowpea skin and yam bark) into powdered form of 200 microns, performance evaluation of the additives was done in the concentration of 1% (5grams), 3% (10grams), 4% (15grams) and 5% (20grams) each for each API standard laboratory batch of mud. All three powders were confirmed to have significant fiber, carbon, oxygen and hydrogen content, enough to affect fluid loss and filtration control. Significant effect was observed in pH, Plastic viscosity, Yield point, Gel strength and cake thickness. The organic additives tested had no significant effect on mud density and specific gravity.Item Influence of Local Additives on Water Based Drilling Mud: A Review(NJEAS, 2023-09-20) Petrus Nzerem; Khaleel Jakada; Mohammed Shariff; Abdulquddus Ozigi; Ayuba Salihu; Ikechukwu Okafor; Steve Adeshina; Khadijah Ibrahim; Adekunle Akanni AdelekeThis review paper focuses on the use of local additives in water-based drilling mud to reduce environmental impact and improve drilling operations. Drilling mud plays a crucial role in drilling operations by acting as a coolant, carrying drilled particles, stabilizing the wellbore, and preventing wellbore issues. However, poorly formulated drilling mud can lead to drilling difficulties and environmental pollution. Therefore, the exploration of organic-based drilling mud additives, sourced locally in Nigeria, is discussed in this paper.it highlights the potential of transforming organic waste materials, such as rice husk, cassava, corn cobs, and more, into usable products for drilling mud. By utilizing these locally sourced organic materials, the environmental impact of drilling waste can be minimized. The importance of waste management in the oil and gas industry is emphasized, as it is crucial for sustainable drilling practices. The paper further discusses various studies and experiments conducted on the use of local polymers and natural materials as substitutes for imported additives in water-based drilling mud. These materials include cassava starches, agro-waste materials, eco-friendly drilling fluid additives, and various plant-based substances. The performance and effectiveness of these materials are evaluated in terms of viscosity control and fluid loss prevention. The results indicate that many of these local polymers and natural materials can be viable and have shown positive results in terms of improving the rheological and filtration characteristics of the mud, reducing fluid loss, and enhancing overall mud qualities. Earlier studies on the use of agro-waste products as additives in drilling fluids are reviewed in this paper. These studies examine the properties affected by local materials, the type of mud used, and the findings of each study. The economic analysis of using agro-waste materials as drilling additives is also discussed. The conclusion highlights the availability and affordability of agricultural waste materials as potential substitutes for traditional drilling additives, which can help reduce drilling costs. The paper also provides recommendations for future research in this area.Item Effect of Raw and Delignified Banana Stem (Musa Cavendish) On the Rheological and Filtration Loss Properties of Water Based Mud(NJEAS, 2023-10-12) Ayuba Salihu; Ahmed Abubakar; Petrus Nzerem; Abdullahi Gimba; Khadijah Ibrahim; Ikechukwu Okafor; Khaleel JakadaIn compliance with environmental laws and safety rules, oil and gas companies have taken necessary steps to eradicate the use of toxic chemicals conventionally used in drilling muds, thereby promoting biodegradable alternatives. This research was carried out to investigate the effect of two banana stem samples; Raw Banana Stem (RBS) and Delignified Banana Stem (DBS) as potential and proficient viscosifiers and fluid loss control agents in water based mud. The rheological properties evaluated include plastic viscosity (cP), apparent viscosity (cP), yield point (Ib/100ft2) and gel strength (Ib/100ft2) at 10 seconds and 10 minutes. Filtration loss properties evaluated include filter cake thickness (mm) and fluid loss volume (ml). Each drilling mud sample was prepared using 350 ml, 20 g bentonite and varying contents (g) of carboxyl methyl cellulose (CMC), RBS and DBS. A mixer was used to mix the mud homogenously; the rheological properties were calculated using a viscometer while the filtration loss properties were calculated using a filter press. The results and analysis were compared to the effects of commercially available carboxymethyl cellulose to validate its properties. RBS and DBS improved the rheological properties of the mud sample contents of 3 g, 5 g, 7 g and 9 g. At contents of 5 g, 10 g, 15 g and 20 g, RBS and DBS samples provide significant fluid loss control and their results are similar to the results of CMC. RBS has a fluid loss volume increase of 6.84 %, 5.69 %, 17.12 % and 8.06 % from CMC’s results at slightly similar filter cake thickness while DBS has a fluid loss volume increase of 15.59 %, 15.09 %, 27.55 % and 15.35 % from CMC’s result. The data obtained from the experiments showed both banana samples can be used as environmentally friendly viscosifiers and fluid loss control agents.Item Analysis of Selected Fiber-Rich Agricultural Waste as Water-Based Drilling Mud Fluid Loss Control Additives(NJEAS, 2024-04-09) Blessing Alade; Petrus Nzerem; Ayuba Salihu; Oghenerume Ogolo; Ajiri OtedhekeFor a drilling operation to be successful, the drilling fluid performance must be optimized. This research study the use of degradable agricultural waste namely cowpea skin powder (CSP), sugarcane rind powder (SRP) and yam bark powder (YP) as additives for fluid loss control. The elemental composition of these food wastes was determined using SEM. Proximate analysis was performed to investigate the content of moisture, ash, nitrogen, protein, volatile matter, fixed carbon, bulk density, specific gravity and pH. The local additives were used at 1% (5grams), 3% (10grams), 4% (15grams) and 5% (20grams) each. For CSP fluid loss increased at 5g and 10g (1% and 3%), by 14% and 9% respectively, at 15g and 10.6g, fluid loss decreased by 33% and 36% respectively. Using SRP of 5g increased fluid loss by 12% but there was decrease in fluid loss with 10g, 15g and 2g in these percentages; 14%, 33% and 37% respectively. YP resulted in fluid loss at 5g giving 1.5% loss, 12% loss with 10grams, 16% fluid loss with 15 grams and 33% filtrate loss with 20grams. Overall, SRP showed best fluid loss performance with 20grams (5%), resulting in 37% fluid loss decrease followed by Yam bark powder at 20grams with fluid loss performance of 33%. The least performance was by CSP at 5grams (3%) that increased the filtrate loss by 14%.Item Production of Fuel Oil from Blends of Refinery Products for Powering Heat Exchanger(NJEAS, 2024-04-21) Aminu Abubakar; Joseph Chior; Ayuba Salihu; Petrus Nzerem; Abdullahi Gimba; Ikechukwu Okafor; Khaleel JakadaFuel oil, also known as furnace oil is a fraction of crude oil obtained when distillation processing is carried out in the refinery. Due to the high viscous of the heavy fuel oil, that makes it difficult to be pump throughout the pipework of the power plant, it is necessary to produce a fuel oil that will meet up the required standard. The aim of this study was to produce fuel oil from the blend of refinery intermediate product which meet certain European fuel specifications outlined in the EN 590:2009 standard alongside NMDPRA Standards. The blending stocks obtained from the Warri Refinery and Petrochemical Company (WRPC) were first filtered to remove some particulate impurities before they were analyzed to determine their properties after which, they were introduced into a mixed-tank that has an agitator connected and the blending was done using the blending ratio obtained from literature. The fuel oil produced was eventually analyzed for properties such as: Specific Gravity, API Gravity, Density, Viscosity, Kinematic Viscosity, Moisture Content, Flash Point, Cloud Point, Pour Point and Sulphur content. The sample with a composition of 33.3% of Decant oil (DCO), 33.3% Heavy gas oil (HGO), 33.3% light cycle oil (LCO) produced fuel oil of specific gravity 0.916, API Gravity 22.95, Density 0.896, Viscosity 40, Kinematic viscosity 4.7, pour point -6.5 and flash point 109, The analysis of the fuel oil meet the standard for blended fuel oil, according to the ISO 8217:2017 Standard. The results confirmed that blending of decant oil with conventional petroleum diesel (heavy and light gas oil) has a highly significant effect on the properties of the resulting fuel blend. The results show that by increasing the heavy gas oil content of the blend, the flash point of the blend increases; while increasing the decant oil content of the blend results in a decrease in Cloud point. The results of the analysis of the produced fuel oil confirms that its properties fall within the acceptable range for Fuel Oil and can be used as fuel for fired heaters and furnaces of the refinery and other process plants.Item MODIFICATION, CHARACTERIZATION AND APPLICATION OF LOCALLY SOURCED ORGANOCLAY FOR OIL SPILL REMEDIATION(NJEAS, 2023-01-01) Ikechukwu Okafor; Roselyn Odimba; Ayuba Salihu; Oghenerume Ogolo; Petrus Nzerem; Abdullahi Gimba; Khaleel JakadaThe Bentonite clay, obtained from Ubakala, Umuahia, in Abia State was investigated as a sorbent for the potential treatment of oil spill in aquatic medium after its modificaion with Dioctadecyl dimethyl ammonium bromide (DODAB). The purified clay sample was subjected to hydrothermal ion exchange reaction to synthesize organoclays under mild reaction conditions. Changes in the microstructural, morphological and physicochemical properties of the modified clay samples were investigated and studied with the use of Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy (EDX). The observations showed the presence of new organic compound groups which indicated that the surfactant was intercalated successfully. The organoclays were further tested in a simulated oil spill situation to assess their potential as oil sorbents and sorbed about 4.5% of the oil that was simulated in the laboratory in water. The results further showed that the synthesized organoclay can be used for the remediation of oil spillage. The organoclays present a cost effective and a suitably environmentally friendly alternative for the remediation of oil spill polluted lands in the Niger Delta region of Nigeria.