Browsing by Author "Jamiu Kolawole Odusote"

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A comprehensive review on the similarity and disparity of torrefied biomass and coal properties
(Elsevier, 2024-05-09) Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Stephen S. Emmanuel; Moses O. Fajobi; Praise Nwachukwu; Ademidun A. Adesibikan; Jamiu Kolawole Odusote; Emmanuel O. Adeyemi; Oluwaseyi M. Abioye; Jude A. Okolie
The use of coal for energy generation is facing serious scrutiny because of environmental concerns. As a result, there is a growing global interest in biomass, a renewable and readily available energy source. However, the utilization of biomass comes with significant drawbacks, including its heterogeneity, low bulk density, and calorific value. Biomass also has a low energy content, high moisture, poor grindability, and high volatile matter, which affect its handling, bulk transportation, and storage. Torrefaction technology has been employed in previous works to improve the properties of biomass for subsequent handling and transportation and for low-cost energy generation. Since coal is a promising precursor for energy generation, it is imperative to compare the physicochemical properties of coal with that of torrefied biomass. Therefore, this study aims to conduct a comprehensive comparison between various grades of coal and torrefied biomass. The review revealed that torrefied biomass could replace coal, as its properties are similar to those of coal, except for high-grade coals. The proximate and ultimate analyses of coals (lignite and bituminous) were found to be comparable to various torrefied biomass materials. The fuel ratio (0.5–2.0), and higher heating values (16,100–19,000 kJ/kg) of coal and torrefied biomass were within the range useful for coal-fired plants. Additionally, ash analyses, ash fusion temperature, hygroscopic tendency, functional group study, and microstructural comparison were reviewed in this study. The results from various studies have shown close similarities with only small disimilarities in the fuel properties between coal and torrefied biomass. Therefore, torrefied biomass is proposed as a complimentary feedstock to coal in various applications.
A COOLING POTENTIAL OF FORMULATED BIO-QUENCHANT OILS ON A CAST ALUMINIUM ALLOY MATERIAL
(Journal of Chemical Technology and Metallurgy,, 2020-02-02) Adebayo Surajudeen Adekunle; Adekunle Akanni Adeleke; Tajudeen Adelani Gbadamosi; Friday O. Nwosu; Jamiu Kolawole Odusote; Peter Olorunleke Omoniyi; Tajudeen O. Popoola; Kazeem Adekunle Adebiyi
The biodegradable vegetable oil based quenchants can serve as cooling media alternative to that of the toxic non-biodegradable petroleum based mineral oil in a heat treatment of aluminium and its alloy. 70 vol. % of edible vegetable oil are blended with 30 vol. % of Jatropha oil to form bio-quenchant oils for Aluminium (Al)-alloy probe treated at 500oC and soaked for 15 min in a muffle furnace. The cooling potential properties such as the cooling rate, the heat transfer coefficient, the Grossman quench severity and the biot number are investigated. The results obtained show that the blended bleached (BB) melon oil provides the highest cooling rate of 49.30oC s-1, while the blended raw (BR) palm oil ensures the lowest cooling rate of 18.45oCs-1. Heat transfer coefficients of 704.6 Wm-2K-1, 432.3 Wm-2K-1, and 394.4 Wm-2K-1 are exhibited by the blended bleached melon oil, the blended raw melon oil and the blended bleached groundnut oil, respectively. They are found higher than that of a petroleum based mineral oil, which amounts to 68.7 Wm-2K-1. The lowest heat transfer coefficient of 272.11 Wm-2K-1 is obtained in case of using a blended raw palm oil. The quench severity of the blended bleached melon oil, the blended raw melon oil and the blended raw groundnut oil refers to a Grossman H-factor of 1.01 m-1, 0.78 m-1, and 0.67 m-1, respectively. The latter values are higher than that obtained in case of a blended raw palm oil, which is equal to 0.37 m-1. However, the heat flow parameters obtained reveal that the blended bleached and the blended raw melon and groundnut oil can be characterized as fast quenching oils, while the blended bleached and the blended raw palm oil can be characterized as medium quenching oils of results comparable to and even better than those of the industrial petroleum based mineral oil.
Advent of Artificial Intelligence in Automotive Engineering
(IEEE, 2024-02-29) Adeiza Avidime Samuel; Adekunle Akanni Adeleke; Esther Nneka Anosike-Francis; Temitayo Samson Ogedengbe; Peter Pelumi Ikubanni; Favour Oluwasayo Adeyemi; Jamiu Kolawole Odusote; Matthew Onuoha; Usman Shuaib
Artificial intelligence (AI) has long been a topic of interest and with its constant development and growing popularity and functions, it is no surprise that it has made its way into the automotive industry. For ages, people have done research regarding AI in the automotive industry, and with the increasing popularity of this subject, the research only goes deeper. This paper gives an analysis of previous research under different areas which involve AI in automotives, somewhat singling out autonomous vehicles. We also go into the basis of artificial intelligence, as well as highlight a few challenges which face the integration of AI into the automotive industry.
Analysis of an Experimental Digital Read-outs Slider Crank Mechanism
(IEEE, 2024-08-15) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Qudus A. Siyanbola; Oluwasogo L. Ogundipe; Olayinka O. Agboola
Slider-crank mechanism (SCM) was developed with digital read-outs in this study to make the reading of experimental results more accurate. They are connected by joints and force elements for the conversion of reciprocating motion into rotary motion or vice-versa. A digital protractor (accuracy = ±𝟎. 𝟐) and a digital vernier caliper (accuracy = +0.02 mm) were incorporated as the crank and the slider respectively, while a stainless-steel plate was made the connecting link. The deviation of the slider (displacement) values from the corresponding theoretical values at various angles was determined. The simple harmonic ratio of the analogue mechanism is higher than that of the digital mechanism but the deviations of the slider (displacement) values of the digital mechanism from the theoretical values are quite negligible. The deviations of the analogue system from its corresponding theoretical values are far higher. Based on the result obtained, the digital system is more precise and accurate for experimental studies than the analogue system.
ANALYSIS OF PROPERTIES OF REINFORCING STEEL BARS: CASE STUDY OFCOLLAPSED BUILDING IN LAGOS, NIGERIA
(Trans Tech Publications, 2012-02-02) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke
The chemical compositions and the microstructures of reinforcing steel bars obtained from three different collapsed building sites were studied. Optical emission spectrometer was used to carry out the chemical analysis, while the microstructure was examined using an optical microscopy. The carbon contents of the steel bars were found to be higher than BS4449 and ASTM706 standards, but they are in close range with the Nst-65-Mn standard. The manganese contents of the steel bars are lower, while the sulphur and phosphorus contents are quite higher than the BS4449, ASTM706 and Nst-65-Mn standards. The hardness values of the investigated bars are higher than recommended BS4449 standard but lower than Nst-65-Mn standard. Brittle globules of Fe3P and FeS were observed within the structure possibly due to higher contents of deleterious sulphur and phosphorus. The results suggest that the investigated reinforcing bars are brittle and thus contributing significantly to the collapse of the building structures.
Assessment of Suitability of Nigerian Made Steel Bars for Structural Applications
(The Journal of the Association of Professional Engineers of Trinidad and Tobago, 2016-10-02) Abdul Ganiyu F. Alabi; Akintunde O. Ayoade; Jamiu Kolawole Odusote; Adekunle Akanni Adeleke
The mechanical properties of selected reinforcing steel bars produced from two rolling mills in Osun State, Nigeria were studied. An optical emission spectrometer was used for chemical composition analysis while the tensile test was carried out using a Universal Testing Machine. Izod v-notched was used for impact test, while the hardness values were obtained from Brinnel hardness tester. Scanning Electron Microscope was used for the fractured surface fractography. The Ultimate Tensile Strengths (UTS) of all the samples are higher than BSS4449:2005+A2:2005 standard and are also in close proximity to A707M-15 standard. Samples A12, B10 and B12 possessed higher yield strengths than samples A16 and B16 but lower than those of BSS4449:2005+A2:2005 and A707M-15 standards. Ductile property of the samples doubled the recommended Nst-65-Mn standard values while the hardness and ductility properties are higher than the recommended A707M-15 and BS4449 standards. The results showed that the investigated reinforcing bar samples possessed reasonably high strength and ductility when compared with available standards. Consequently, these bars would be suitable for structural applications where strength and ductility are critical properties. They would also be used in steel reinforcement applications that would require continuous and repetitive loading such as in buildings and bridges.
ASSESSMENT OF TRIBOLOGICAL PROPERTIES OF STIR CAST Al6063 ALLOY REINFORCED WITH OKABA COAL ASH
(SCICELL, 2023-03-23) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Qudus Badrudeen; Adeiza Avidime Samuel; Olalekan Ogunniyi; Temitayo Samson Ogedengbe
Composite are multi-phase materials made up of matrix and reinforcement. This paper assesses the tribological property of Al6063 alloy (AMCs) reinforced with Okaba coal ash (OCA) using the stir casting method. By using a constant speed of 1000 rpm and two different loads (250 g and 750 g) on Taber wear apparatus, the tribological properties of the produced composite are contrasted with those of an unreinforced Al6063 alloy. The results show a reduction in wear index and the highest abrasion resistance at 4 wt.% coal ash at 500 g and 1000 rpm, as well as at 0, 2, and 6 wt.% with 8.688, 5.878, and 5.813 at 500g and 8.688, 5.878, 4.125, and 5.813 at 750g, respectively. Therefore, for all composite products compared to metal, there is an increase in abrasion resistance with a decrease in wear index, but this decreases when the load is increased to 750g, showing that the higher the load, the higher the wear index, which results in a reduction in abrasion resistance. Load is taken into greater consideration when using the AMCs manufactured in engineering applications. Additionally, SEM images revealed uniform distribution of the OCA reinforcement in the matrix alloy; thereby, improving its wear resistance.
Chemical and Mechanical Properties of Reinforcing Steel Bars from Local Steel Plants
(Springer, 2019-06-06) Jamiu Kolawole Odusote; Wasiu Shittu; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Olumide Adeyemo
Steel bars are important engineering materials for structural application. In Nigeria, due to incessant building collapse occurrences, it is important to further investigate some of the mechanical and chemical properties of reinforcing steel bars produced from scrap metals in order to ascertain their compliance with the required standard. Three diameters (10, 12 and 16 mm) of the reinforcing steel bars were chosen from each of the eight steel plants (A–H). Chemical composition analyses and mechanical tests (yield strength, ultimate tensile strength and percentage elongation) were performed using optical emission spectrometer and Instron Satec Series 600DX universal testing machine, respectively. Hardness values of the samples were obtained by conversion of tensile strength based on existing correlation. The results showed that carbon contents, hardness values, yield and ultimate tensile strengths of some of the steel bars were found to be higher than the BS4449, NIS and ASTM A706 standards. The steel bar samples were also found to possess good ductility with samples from steel plants C and D. By observation, all the 12 mm steel bars from steel plants A to H met the required ASTM and BS4449 standards except samples from plant G. This study revealed that most of the investigated reinforcing steel bars have reasonable yield strength, ultimate tensile strength, ductility and hardness properties when compared with the relevant local and international standards. Therefore, they are suitable for structural applications where strength and ductility will be of paramount interest
DEVELOPMENT AND ASSESSMENT OF PARTICLE REINFORCED ABRASIVE GRINDING DISCS FROM LOCALLY SOURCED MATERIALS
(Journal of Chemical Technology and Metallurgy, 2024-09-09) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Timothy Adekanye; Adeiza Avidime Samuel; Chinedum Oji
Management of waste materials is a serious concern to researchers and scientists. Waste materials cause health and environmental hazards. Hence, they should be properly managed. The aim of this study is to develop a grinding disc using agricultural wastes (palm kernel shell and snail shell), granite, aluminium oxide, and polyester resin. The particles of snail shell, palm kernel shell, aluminium oxide (abrasive) and granite (friction modifier) were measured in percentages varying between 8 - 29 wt. % and were mixed with 27 wt. % polyester resin (binder), 3 wt. % methyl ethyl ketone peroxide (hardener) and 3 wt. % cobalt naphthalene (accelerator) to produce a grinding disc. The micrograph, hardness, wear rate, and water absorption tests were carried out on the grinding disc samples. The result showed that the composition with the highest palm kernel shell particle content (29 wt. %) had the best values for hardness and wear resistance, making it the most suitable material for grinding discs. The environmentally-friendly palm kernel shell-based discs could be used for soft metals, wood grinding and finishing processes.
Effect of copper addition and solution heat treatment on the mechanical properties of aluminum alloy using formulated bio-quenchant oils
(Engineering and Applied Science Research, 2020-01-01) Adekunle A.S.; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Omoniyi P. O.; Gbadamosi T. A.; Jamiu Kolawole Odusote
Addition of copper and use of solution heat treatment solution with bio degradable vegetable oils as quenchants has great potential to improve the mechanical properties of aluminum and its alloys. In this study, copper was added to as-received Al- Si-Mg alloy to produce Al-Si-Cu-Mg alloy. The specimens were quenched with blended bleached bio-quenchant oils and a petroleum-based oil after solution heat treatment. The alloy was heat treated at 500℃, soaked for 20 minutes in a muffle furnace before quenching in the formulated bio-quenchant oils. The cooling properties, mechanical properties and microstructure of the solution treated specimens were determined. Blended bleached melon (BBM) oil was observed to have offered a higher cooling rate of 49.3 ℃ s-1 compared to the petroleum-based (PB) oil with a cooling rate of 25.8 ℃ s-1. Blended bleached melon oil exhibited the highest quench severity value of 1.0074 m-1, while petroleum-based oil was 0.6133 m-1. The as-received alloy and as-cast alloy specimens exhibited tensile strength values of 125.33 and 131.37 N mm-2, respectively, while a higher tensile strength value of 139.30 Nmm-2 was obtained using the blended bleached melon oil. The highest Rockwell hardness number, 61.00 HRB, was obtained using blended bleached melon oil. The overall mechanical properties of specimens improved after the addition of copper and heat treatment in various bio-quenchant oils
Essential basics on biomass torrefaction, densification and utilization
(Wiley, 2020-09-24) Adekunle Akanni Adeleke; Jamiu Kolawole Odusote; Peter Pelumi Ikubanni; Olumuyiwa A. Lasode; Madhurai Malathi; Dayanand Paswan
Torrefaction and densification are crucial steps in upgrading biomass as feed-stock for energy generation and metallurgical applications. This paperattempts to discuss essential basics on biomass torrefaction and densification,which can propel developing nation to take full advantage of them. The mostpromising clean energy sources that have found applications in various areasare biomass materials, that is, both the lignocellulosic and non-lignocellulosi c.However, high moisture contents, low energy density, hydrophilic nature, poorstorage and handling properties are the major drawbacks limiting its useful-ness. Therefore, torrefaction as one of the major thermal pre-treatment pro-cesses to upgrade biomass in terms of improved energy density, hydrophobic,moisture content and grindability has been discussed. The influence of temper-ature, residence time, particle sizes and gas flow rates on the properties of tor-refied biomass has also been discussed. The advantages and disadvantages ofvarious torrefaction technologies have also been highlighted. The possibleareas of application of torrefied biomass especially densification into pelletsand briquettes alongside the equipment required for it have been reviewed inthis paper. The torrefied biomass can be deployed in the metallurgical indus-tries as reducing agent in the development of sponge iron from iron ores ofvarious grade including lean ones. The information gathered in this paperfrom peer-reviewed articles will reduce the burden of seeking to understandthe preliminaries of torrefaction process and its importance
Evaluation of Non-Isothermal Kinetic Parameters for Pyrolysis of Teak Wood using Model-Fitting Techniques
(TRENDS IN SCIENCES, 2021-12-21) Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Jamiu Kolawole Odusote; Thomas Orhadahwe; Olumuyiwa A. Lasode; Samuel Adegoke; Olanrewaju Adesina
Teak wood is one of the prominently used raw material in the construction industry, thus contributing extremely to the biomass waste available in Nigeria. These wastes are usually used for energy generation that requires upgrade into better fuel before application. Hence, the present study evaluates the non-isothermal kinetic parameters for pyrolysis of teak wood using model-fitting techniques. Teak wood dust was subjected to proximate, ultimate and calorific value analyses based on different ASTM standards. The thermal degradation and decomposition behaviour of the teak wood dust was examined using a thermogravimetric analyzer. Pulverized teak (6.5 mg) was heated from 30 to 800 ºC at varying heating rates (5, 10 and 15 ºC) in an environment where 100 mL/min of nitrogen gas was charged in continuously to maintain an inert condition. Avrami-Erofeev, Ginstling-Broushtein (GB) and Mampel models were used to evaluate the kinetic parameters of the pyrolysis of teak wood dust. The teak wood dust contained 7.25 % moisture, 79.26 % volatile matter (VM), 1.74 % ash and 11.75 % fixed carbon. The calorific value of the wood dust was 18.72 MJ/kg. The results of the thermogravimetric analyses depicted that heating rate has no effect on weight loss during the reactive drying zone. However, as the thermal treatment progressed into the active pyrolysis and passive pyrolysis zones, the weight loss decreased with increase in heating rate. The devolatilization parameters also increased with heating rates except for the maximum conversion. The results of the kinetic parameters evaluation revealed that the GB model was best fit to evaluate the kinetic parameters of teak in the active pyrolysis zone while GB and Mampel models were considered most appropriate for the evaluation of the kinetic parameters in the passive pyrolysis zone. Model-fitting method has the capacity to capture a wide range of fractional conversion at a glance
Evaluation of the Mechanical Properties of Reinforcing Steel Bars from Collapsed Building Sites
(ASM, 2013-08-27) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke
Mechanical properties of reinforcing steel bars obtained from three different collapsed building sites in Lagos, Nigeria were examined. An optical emission spectrometer was used for chemical composition analysis while the tensile test was carried out using a Universal Testing Machine. The yield strength of the steel bars was found to be higher than BS4449 (GRADE 460B), Nst.65-Mn, and ASTM A706 standards, while their percentage elongations were lower than most of the standards. The steel bars used at the Sango collapse site have higher UTS compared with the standards, while those used at Ilesanmi and Ewuntun collapse sites have UTS values that are in close range with the standards. The reinforcing bar obtained from Ilesanmi collapsed site has higher percentage elongation than ASTM A706 standard but lower than Nst.65-Mn and BS4449 (GRADE 460B) standards. The bars obtained from Sango and Ewuntun collapse sites displayed lower percentage elongation compared with that from Ilesanmi site. All the investigated reinforcing bars possessed reasonably high strength with low ductility. Thus, these bars are susceptible to brittle fracture, which might have contributed to the collapse of the building structures.
Formed Coke from Coal and Plastic: A Review
(IEEE, 2023-02-28) Adekunle Akanni Adeleke; Petrus Nzerem; Ayuba Salihu; Jamiu Kolawole Odusote; Adebayo Isaac Olosho; Peter Pelumi Ikubanni; Yazeed Abubakar Mohammed; Samuel Chijoke Lawrence; Temitayo Samson Ogedengbe; Adeiza Avidime Samuel
Influence of sawdust ash on the microstructural and physicomechanical properties of stir‑cast Al6063/SDA matrix composite
(The International Journal of Advanced Manufacturing Technology, 2023-02-02) Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Jamiu Kolawole Odusote; Boluwatife B. Olujimi; Jude A. Okolie
Mechanical, physical, and corrosion properties of pure aluminum cannot meet the requirements of the modern industries. This has led to increase in demand for aluminum alloys and aluminum matrix composites with enhanced properties. These properties make them suitable for most applications. This article analyzes the physicomechanical and microstructural properties of stir cast Al6063 alloy matrix reinforced with different weight fractions (2, 4, and 6 wt.%) of sawdust ash (SDA). The density, porosity, hardness, tensile strength, and impact strength of the unreinforced alloy and developed composite samples were evaluated while microstructural analysis was also carried out. The results showed reduced density values with increased SDA contents while percentage porosity ranged between 1.56 and 2.23%. The hardness (88.3–106.93 BHN) and tensile strength (112.13–132.71 MPa) of the composites were 21.09% and 18.35% better than those of Al6063 alloy. However, the impact strengths (45.48–35.51 J) of the composites were lower when compared to the unreinforced Al6063 alloy with a reduction of 21.92%. Microstructural images showed evenly distributed reinforcement particles within the matrix, while the XRD analysis also revealed the presence of different intermetallic phases in the composite samples. The micrographs of the composites showed plastic deformation during straining. The findings from the study indicate that SDA particulates incorporated into alloy matrix influenced the properties with increased hardness and tensile strength and reduced impact strength. Hence, the aluminum matrix composites will be suitable for use in lightweight engineering applications.
INFLUENCE OF TORREFACTION ON LIGNOCELLULOSIC WOODY BIOMASS OF NIGERIAN ORIGIN
(Journal of Chemical Technology and Metallurgy, 2019-02-02) Adekunle Akanni Adeleke; Jamiu Kolawole Odusote; Paswan Dayanand; Lasode Olumuyiwa Ajani; Malathi Madhurai
Torrefaction process is a thermal treatment that can improve quality of lignocellulosic biomass into a carbon-rich and hydrophobic feedstock which is applicable as fuel and metallurgical reductant. Biomass (Melina and Teak wood) of Nigerian origin was subjected to mild (240o C) and severe (300o C) torrefaction treatment at different residence times (30 and 60 min) and particle sizes (+0.5 - 2 mm and +4 - 6.35 mm). Raw biomass and biochar from torrefaction were subjected to proximate, ultimate, higher heating value and SEM analyses. The mass yield obtained for mild treatment conditions for both biomass was in the range of 72 - 84 (wt. %) compared to 40 - 54 (wt. %) under severe treatment conditions. However, 33 - 56 % increment in higher hating value was observed for severe treatment conditions as against 11 - 17 % of mild treatment condition. This ultimately led to a 60 - 72 (wt. %) energy yield for severe treatment conditions and 73 - 94 (wt. %). The fixed carbon content increased from the range of 8 - 11 (wt. %) to 20 - 61 (wt. %) after torrefaction. The volatile matter content under mild condition was reduced by 7 - 10 % for both biomass as against 41 - 47 % under severe treatment condition. The fuel ratio increased from 0.11 and 0.15 for Melina and Teak woods respectively to a range of 0.22 - 0.25 for mild treatment conditions and 0.97 - 1.75 for severe treatment condition. The H/C and O/C atomic ratios of biochar were lowered towards that of sub-bituminous coal and peat. A honey-comb-like structure with cylindrical holes were observed for biochar compared to the fibrous and spongy nature of the raw biomass. Biomass of Nigerian origin were improved under torrefaction and thus can be suitable as feedstock in thermal or metallurgical applications.
Inhibition efficiency of gold nanoparticles on corrosion of mild steel, stainless steel and aluminium in 1M HCl solution
(Elsevier, 2021-01-01) Jamiu Kolawole Odusote; Adeolu Adesoji Adediran; R.A. Yahya; Adekunle Akanni Adeleke; J.G. Oseni; J.M. Abdul; Tesleem B. Asafa; S.A. Adedayo
In this study, the influence of gold nanoparticles (AuNPs) on corrosion behavior of mild steel, aluminium and stainless steel in 1.0 M HCl was investigated. The nanoparticles were previously characterized using FTIR, UV–Vis and TEM. Five concentrations of AuNPs solution (0 µg/ml, 5 µg/ml, 10 µg/ml, 15 µg/ml, 20 µg/ml) were added to 1M HCl. The corrosion rates of the metal samples and inhibition efficiency of the nanoparticles were analyzed using gravimetric (weight loss) and potentiodynamic polarization techniques. After 2000 h of exposure, gravimetric study showed that weight loss was reduced by ∼75% translating to ∼85% reduction in corrosion rate for the solution containing 20 µg/ml of AuNPs. The equivalent inhibition efficiency was 88%, 98% and 96% for aluminium, mild steel and stainless steel, respectively. Furthermore, potentiodynamic polarization results showed that the presence of AuNPs modified the mechanism of anodic dissolution by the formation of adsorption layer on the surface of the metal samples. These results indicated that AuNPs can be incorporated into existing inhibitors towards minimizing corrosion rate.
Inhibition potential of silver-gold nanoparticles on mild steel in 3.5% NaCl solution
(Engineering and Applied Science Research, 2023-01-01) Peter Pelumi Ikubanni; Adekunle Akanni Adeleke; Jamiu Kolawole Odusote; Tesleem B. Asafa; Sharafadeen K. Kolawole; Victor O. Ogbesanya; Jude A. Okolie
This study investigates the corrosion behaviour of silver-gold nanoparticles as an inhibitor on the degradation of mild steel in 3.5% NaCl (saline environment) using gravimetric analysis and potentiodynamic measurement. The inhibitor Ag-AuNPs was synthesized from Kola nut pod. Five different concentrations of the Ag-AuNPs solution (0, 5, 10, and 20 μg/ml) were added to the saline environment. The gravimetric result showed that inhibition efficiency of 83.33% was the highest at 20 μg/ml of Ag-AuNPs inhibitor concentration. The Tafel polarization result showed that the solution with 20 μg/ml of Ag-AuNPs had the highest inhibition efficiency of 99.465%. At 0 μg/ml of Ag-AuNps, the surface morphologies of the mild steel sample did not show the existence of Ag-AuNps constituent in the saline environment containing the nanoparticles. The outcome showed that the saline environment with 15 and 20 μg/ml of Ag-AuNPs could successfully limit the corrosion of the mild steel.
Magnesium inclusion effect on Al-Zn-Cu alloys: A study on microstructure and mechanical properties
(Elsevier, 2021-04-14) Jamiu Kolawole Odusote; Adekunle Akanni Adeleke; S.A. Muraina; Peter Pelumi Ikubanni; Ibrahim Momoh-Bello Omiogbemi
The microstructure and mechanical properties of Al-Zn-Cu alloy with magnesium inclusion varying between 0.5 and 1.5 wt% were explored in this investigation. Al-Zn-Cu-Mg alloy was prepared by sand casting. Heat-treatment was done on the cast alloy samples at 460 °C for 2 h, which was then water-quenched. The samples at 160 °C were age-hardened for 5 h. Mechanical tests were done on both the heat-treated and as-cast alloy samples. Optical and scanning electron microscopy were used for the surface morphology of the samples. The maximum tensile strength (178.04 N/mm2) and hardness value (42.49 HB) were obtained from the Al-Zn-Cu-Mg alloy samples with 0.33 wt% Mg and 0.001 wt% Mg, respectively. In the as-cast samples, the reinforcing intermetallic phases present was coarse in nature while the precipitation hardened samples showed well-distributed reinforcing intermetallic phases which are fine grain size. Hence, the tensile strength of the cast Al-Zn-Cu-Mg alloy was positively influenced with the addition of magnesium while precipitation hardening eliminates micro segregations, thus, Al-Zn-Cu-Mg alloy mechanical properties were improved. Thus, the Al-Zn-Cu-Mg alloy can be useful in automobile industry.
Mechanical properties and microstructural evaluation of heat-treated aluminum alloy using formulated bio-quenchants
(Akademiai Kiado, 2020-10-03) A. S. Adekunle; Tajudeen Adelani Gbadamosi; P.O. Omoniyi; Adekunle Akanni Adeleke; Peter Pelumi Ikubanni; Jamiu Kolawole Odusote
Heat treatment industries require various quenching media to improve the properties of the materials to be quenched. Petroleum based mineral (PBM) oil, a non-biodegradable oil, is popular amongst others quenchants in heat treatment processes. Recently, biodegradable oils mostly in their raw, unblended and unbleached forms have been employed for quenching of various engineering materials. Therefore, the present study examined the effects of some selected bio-quenchants in blended raw (BR) and blended bleached (BB) forms on the mechanical properties and microstructure of solution heat treated aluminum (Al)-alloy. Edible vegetable oil (70% by volume) was blended with 30% by volume of jatropha oil to form the bio-quenchant oils. Another set of bio-quenchants were formed by bleaching the raw oils before mixing so as to reduce the oxidation level and contaminations in the oil. The Al-alloy is solution heat treated at 500 °C and soaked for 15 min in an electric muffle furnace before quenching in the various established bio-quenchants. Results showed that samples treated in blended raw melon (BRM) oil have higher tensile strength of 151.76 N/mm while samples quenched in blended bleached melon (BBM) oil have higher hardness value of 61.00 HRC. In accordance to the results obtained the bio-quenchants were found to be effective replacement to the PBM oil.